Large, weakly basic bis(carboranyl)phosphines: an experimental and computational study
نویسندگان
چکیده
منابع مشابه
Large, weakly basic bis(carboranyl)phosphines: an experimental and computational study.
The bis(carboranyl)phosphines [μ-2,2'-PPh-{1-(1'-1',2'-closo-C2B10H10)-1,2-closo-C2B10H10}] (I) and [μ-2,2'-PEt-{1-(1'-1',2'-closo-C2B10H10)-1,2-closo-C2B10H10}] (1) have been prepared and spectroscopically and structurally characterised. Crystallographic and DFT computational studies of 1 suggest that the orientation of the ethyl group, relative to the bis(carborane), is the result of intramol...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2017
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c7dt00485k